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Issue Info: 
  • Year: 

    2014
  • Volume: 

    17
Measures: 
  • Views: 

    103
  • Downloads: 

    58
Keywords: 
Abstract: 

IONIC LIQUIDS (ILS) HAVE ATTRACTED MANY RESEARCHERS IN THE AREAS INCLUDING PHYSICS AND CHEMISTRY BECAUSE OF THEIR CHARACTERISTICS THAT ARE DIFFERENT FROM CONVENTIONAL MOLECULAR LIQUIDS. ILS ARE LIQUID AT OR NEAR ROOM TEMPERATURE, AND SHOW NEGLIGIBLE VAPOR PRESSURE, THERMAL AND CHEMICAL PROPERTIES. ALSO, ILS HAVE BEEN WIDELY USED AS SOLVENTS FOR ORGANIC REACTIONS WITH THE EXPECTATION OF HIGH YIELDS...

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Issue Info: 
  • Year: 

    2013
  • Volume: 

    16
Measures: 
  • Views: 

    112
  • Downloads: 

    80
Abstract: 

INTRODUCTION: USAGE OF CUBIC EQUATIONS OF STATE (EOS) SUCH AS PATEL-TEJA (PT) EOS REMAINS COMMON IN THE INDUSTRY IN SPITE OF RECENT ADVANCEMENTS IN THE FIELD OF EQUATION OF STATE. IT HAS ALREADY BEEN PROVED THAT SUCH CLASSICAL EOS WHICH FOLLOWS A MEAN FIELD APPROACH FAIL TO DISPLAY PHYSICAL PROPERTIES IN THE VICINITY OF THE CRITICAL POINT. IN ADDITION, IT IS KNOWN THAT IN THIS AREA THE REPRESENTATION OF THERMODYNAMIC PROPERTIES MUST RELY ON SCALE INVARIANCE. THE DEVELOPMENT OF A UNIVERSAL MODEL FOR THE DESCRIPTION OF THE THERMODYNAMIC PROPERTIES OF FLUIDS OVER A WIDE RANGE OF PARAMETERS OF STATE INCLUDING THE IDEAL GAS LIMIT AND THE CRITICAL REGION HAS ALWAYS BEEN ONE OF THE MOST DIFFICULT TASKS OF THE THEORY OF FLUIDS.

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Issue Info: 
  • Year: 

    2004
  • Volume: 

    9
Measures: 
  • Views: 

    153
  • Downloads: 

    0
Abstract: 

A NEW THREE PARAMETER CUBIC EQUATION OF STATE WAS DEVELOPED BASED ON GENERALIZE VAN DER WAALS THEORY [1] AND FOCUSED ON A MODIFICATION OF ATTRACTIVE PRESSURE TERM OF VAN DER WAALS EQUATION. IT HAS ONE TEMPERATURE DEPENDENT PARAMETER CALLED A(T) AND OTHERS ARE CONSTANT. THE VALUE OF A(T) WAS EVALUATED BY MINIMIZING SATURATED LIQUID DENSITY DEVIATION FROM EXPERIMENTAL VALUE AND SATISFYING THE VAPOR LIQUID EQUILIBRIUM CONDITION SIMULTANEOUSLY. THEN A(T) WAS FITTED AGAINST REDUCED TEMPERATURE, EXPERIMENTAL COMPRESSIBILITY FACTOR AND PITZER ACENTRIC FACTOR.THE NEW EQUATION HAS ADVANTAGES OF BOTH ACCURACY AND SIMPLICITY. THE RESULTS OF CALCULATION FROM THE NEW EQUATION OF STATE SHOW A BETTER PREDICTION OF SATURATED LIQUID DENSITY AND VAPOR PRESSURE TO SOME OTHER EQUATIONS OF STATE SUCH AS PENG ROBINSON AND PATEL TEJA, ESPECIALLY IN NEAR CRITICAL REGION.

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Author(s): 

SALEHPOUR A.R. | NASRIFAR KH.

Journal: 

Issue Info: 
  • Year: 

    2008
  • Volume: 

    42
  • Issue: 

    2 (112)
  • Pages: 

    257-268
Measures: 
  • Citations: 

    0
  • Views: 

    1294
  • Downloads: 

    189
Abstract: 

In this contribution, two approaches are followed to predict the saturated liquid density of liquefied natural gas (LNG) mixtures. In one approach, 12 cubic equations of state (EoSs), comprising the popular Peng-Robinson (PR) and Redlich-Kwong-Soave (RKS), are employed to predict the saturated liquid density of 20 LNG mixtures. In the other approach, these EoS are used in conjunction with a recently developed correlation to predict the liquid density of the same LNG mixtures. This correlation takes the advantages of the EoSs functions and is remarkably accurate for LNG mixtures. The results for both approaches are presented and the best predicting methods are ranked. Also the liquid density of 3 gas condensate mixtures are predicted using 10 EoSs and the results are compared with experimental data. The method employed is discussed and the best EoSs are ranked. Our evaluation indicates that in general, the EoSs used in this study are not accurate enough for predicting the liquid density of gas condensate mixtures. The PR, PATEL-TEJA (PT) EoSs or one of their variant are recommended, however

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Issue Info: 
  • Year: 

    2013
  • Volume: 

    2
Measures: 
  • Views: 

    278
  • Downloads: 

    163
Abstract: 

THIS PAPER COMPARES THE EFFECTS OF USING VARIOUS TYPES OF EQUATIONS OF STATE SUCH AS PENG RABINSON(PR), PREDICTIVE SOAVE RIDLICH KOWNG (PSRK), BENEDICT–WEBB–RUBIN-STARLING (BWRS), NASRIFAR-BOLAND(NB), AND VALDERRAMA -PATEL -TEJA (VPT) ON RATE OF DOUBLE GAS HYDRATE FORMATION BASED ON THE KASHCHIEV AND FIROOZABADI MODEL FOR GASEOUS MIXTURES SUCH AS 65% C1/35 %C3, 35% C1/65% C3, 65% C1/35 % I-C4, 35% C1/65% I-C4 WITH EXPERIMENTAL DATA POINTS OBTAINED IN A FLOW MINI-LOOP APPARATUS WITH OR WITHOUT THE PRESENCE OF KINETIC INHIBITORS AT VARIOUS PRESSURES AND SPECIFIED TEMPERATURE. FOR THE PREDICTION OF THE GAS CONSUMPTION RATE FOR DOUBLE GAS HYDRATE FORMATION IN A FLOW MINI-LOOP APPARATUS, THE RATE EQUATION BASED ON THE KASHCHIEV AND FIROOZABADI MODEL FOR SIMPLE GAS HYDRATE FORMATION IN BENCH SCALE WAS DEVELOPED. THE TAAD% WAS FOUND TO BE 18.6 %, 18.8 %, 19.8%, 20.2% AND 20.7% FOR THE PR, NB, PSRK, VPT AND BWRS EQUATIONS OF STATE FOR CALCULATING GAS CONSUMPTION IN DOUBLE GAS HYDRATE FORMATION IN THE PRESENCE AND ABSENCE OF KINETIC HYDRATE INHIBITORS, RESPECTIVELY. COMPARISON RESULTS BETWEEN THE CALCULATED AND EXPERIMENTAL DATA POINTS OF GAS CONSUMPTION INDICATE THAT THE PR AND NB EQUATIONS OF STATE HAVE LOWER ERRORS THAN THE PSRK, VPT AND BWRS EQUATIONS OF STATE FOR THIS MODEL.

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Issue Info: 
  • Year: 

    2017
  • Volume: 

    40
  • Issue: 

    SUPPLEMENT 1/1
  • Pages: 

    229-238
Measures: 
  • Citations: 

    0
  • Views: 

    968
  • Downloads: 

    0
Abstract: 

In this paper, the effect of tube diameter (Dp) in measurement of shear stress (tb) of the boundary layer wall was investigated under a zero pressure gradient. For this purpose, four different tubes with outside diameters of 3.2, 3.9, 4.7 and 6.3 mm were used which are corresponded to Dp/d of 0.039, 0.047, 0.057 and 0.076, respectively. Measurement of the pressure difference of static point and total in Preston tube was implemented using a differential pressure transducer with accuracy of 0.2 percent of the original scale. The results of the shear stress measurements around Reynolds numbers from 6.4´104 to 39.87´104 using PATEL and Bechert calibration equations showed that the Preston tube diameter has a significant impact on the shear stress estimation and both equations are sensitive to the tube diameter. The maximum value of difference in the shear stress measurementstb of different tubes using PATEL calibration is about 9%, while the Bechert calibration gives a maximum difference of approximately 14%. Comparing results obtained from both PATEL and Bechert calibration equations showed that variation in result of the two equations is minimum when the diameter Preston tube is 3.9 mm.

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Author(s): 

LIU JIN LIN

Issue Info: 
  • Year: 

    2013
  • Volume: 

    39
  • Issue: 

    1
  • Pages: 

    107-124
Measures: 
  • Citations: 

    0
  • Views: 

    465
  • Downloads: 

    143
Abstract: 

Making use of an extended fractional differintegral operator (introduced recently by PATEL and Mishra), we introduce a new subclass of multivalent analytic functions and investigate certain interesting properties of the subclass.

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Issue Info: 
  • Year: 

    2010
  • Volume: 

    7
  • Issue: 

    4
  • Pages: 

    42-49
Measures: 
  • Citations: 

    0
  • Views: 

    304
  • Downloads: 

    0
Abstract: 

Ibuprofen solubility in supercritical carbon dioxide was measured using a dynamic apparatus at a pressure between 80 and 140 bars at three different temperatures, 308.15, 313.15 and 318.15 K. The mole fraction of Ibuprofen in fluid phase was in the range of 0.015 × 10-3 - 3.261 × 10-3 at the mentioned operational condition. Modified Mendez-Santiago and TEJA equation were used to check the consistency of the experimental data. Results were correlated using the Stryjek and Vera equation of state with the van der Waals 1-parameter (vdW1) and 2-parameters (vdW2) mixing and combining rules. Interaction parameters along with the percentage of the average absolute relative deviation (%AARD) were displayed. Also, the Lydersen group contribution methods were used for predicting the physicochemical and critical properties of the Ibuprofen.

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Issue Info: 
  • Year: 

    2018
  • Volume: 

    16
  • Issue: 

    52
  • Pages: 

    1-13
Measures: 
  • Citations: 

    0
  • Views: 

    456
  • Downloads: 

    0
Abstract: 

Young's modulus of blends of thermoplastic polyurethane (TPU) and acrylonitrile butadiene styrene (ABS) are measured with different weight percentage (blend ratio). The results of the different micromechanical models prediction of Young's modulus، based on both droplet matrix and co-continuous morphology، are compared with experimental results. Both two-dimentisional models like series، parallel، Maxwell، Halpin-Tsai، Takayanagi، Davis، Coran and PATEL، and three-dimensional models like Kolarik، Barentson and Nijhof are used for Young's modulus prediction of polymer blends. In this work، an emphasis was given to the effect of weight percentage on morphology and mechanical properties of the blend. Scanning electronic microscopy shows droplet matrix morphology in the presence of less than 20 wg% ABS in TPU matrix but in 70/30 TPU/ABS blend ratio، ABS phase dispersed like elongated elliptical and phase inversion happened. In the 95/5، 90/10 and 80/20 blend ratio which ABS droplets dispersed uniformly throughout the TPU matrix، Parallel Takayanagi and Barentson series model of parallel parts، could predict Young's modulus with good accuracy. In the 70/30 blend ratio which phase inversion was observed and both phases are somehow continuous، Coran-PATEL، series Nijhof and Kolarik models were accurate.

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